Asher,
I'll try to give some background in my broken english.
The shoot was made in a break during a fashion shoot for a friends boutique. She was really angry about something I forgot and I've tried to get her laughing. As she looks like this I ask her to keep the expression, move the light stand closer to her, because we moving too much in the set, grab for the Camera and take the shoot. After the Shutter releases, she breaks out laughing loud... ...the expression we see has really nothing to do with the situation it comes from.
The Lighting is only one 8" reflector with a 30º grid attached about 1 1/2m above her and a bouncer laying on the floor, to get a catch light in the eyes. I use a ND Filter to shoot wide open (f3.2). The BG is terribly overexposed due to a seamless white setup (Two hidden flashes pointing to the BG) and to little distance. The light on the (images) right of her face is from the background light too. We move around to much while joking and she doesn't give a second chance to me...
The post processing consists of playing around with gradiation curves only. I don't really like much post processing.
One of the ideas for the shoot was to show a real human wearing the clothes. The series isn't that harsh like this shot, off course. I'll ask for permission to show some of the images.
Thank you for watching
Giorgio